维基百科

二烃基硼酸

二烃基硼酸是硼酸的两个羟基被烃基取代得到的有机硼化合物，其通式为R2BOH。它的羟基氢被烃基取代，可以得到二烃基硼酸酯（R2BOR'）。

二烃基硼酸的结构通式

二烃基硼酸及其衍生物

常见的物质见列表：

R2BOR' 酸 R'=H 酸酐 酯R'
R 氢（H） 氧（-O-） 氨基乙基 乙基 正丙基 正丁基 3-甲基丙基 1-甲基丙基 苯基 乙二氧二基 甲基 8-喹啉基
苯基  Y [1]  Y cas 524-95-8  Y cas 43185-52-0  Y  Y cas 15323-04-3  Y  Y  Y  Y cas 13471-36-8 SID 535455
o-甲苯基  Y  Y
m-甲苯基  Y
p-甲苯基  Y[2]  Y
p-茴香基  Y  Y[3]  Y
p-联苯基  Y  Y[4]  Y
p-氯苯基  Y cas 89566-59-6  Y[5]  Y cas 61733-90-2  Y cas 564483-61-0
3-氯苯基  Y cas 433338-06-8
α-萘基  Y  Y[6]  Y[7] cas 6962-88-5
β-萘基  Y  Y[3]
p-溴苯基  Y  Y[3]  Y[8]
2-甲基-5-氯苯基  Y  Y[5]
2-噻吩基 [9] SID 3881207 SID 8142470
mesityl sid 4278417 CAS 20631-84-9[10][11][12]
甲基  Y cas 13061-97-7  Y cas 86610-16-4  Y cas 4443-43-0
乙基  Y cas 4426-31-7  Y[13] 7318-84-5  Y cas 7397-46-8
烯丙基  Y
正丁基  Y cas 1189-31-7  Y[14] cas 19324-14-2  Y cas 2344-21-0  Y  Y  Y  Y  Y  Y cas 2344-21-0
4-甲基丁基  Y
2-氯乙烯基  Y  Y[15]
3,5-二甲基苯基  Y[16]
丙基  Y cas 53678-60-7  Y cas 2938-89-8
1-甲基丙基 cas 4026-69-1
2-甲基丙基 cas 4026-82-8

参考文献

  1. ^ Lange, Thomas; Böhme, Uwe; Roewer, Gerhard. Crystal structure of tetraphenyldiboroxane a monomer diboroxane. Inorganic Chemistry Communications. 2002, 5 (6): 377–379. doi:10.1016/S1387-7003(02)00402-1. 
  2. ^ Erbes, Michael; Klaus Forstinger; Andreas Meudt. Process for preparing boronic and borinic acids. US Patent 20020161230. 31 Oct 2002 [15 October 2013]. （原始内容存档于2016-03-06）. 
  3. ^ 3.0 3.1 3.2 Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始内容 (PDF)存档于2016-03-05）.  ref 24
  4. ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始内容 (PDF)存档于2016-03-05）.  ref 25
  5. ^ 5.0 5.1 Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始内容 (PDF)存档于2016-03-05）.  ref 26
  6. ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始内容 (PDF)存档于2016-03-05）.  ref 5
  7. ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始内容 (PDF)存档于2016-03-05）.  ref 9
  8. ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始内容 (PDF)存档于2016-03-05）.  ref 2
  9. ^ Low, John Nicolson; Musgrave, Oliver; Wardell, James. (2-Aminoethoxy)bis(2-thienyl)boron. Acta Crystallographica Section C. 15 February 2000, 56 (2): e63. doi:10.1107/S0108270100000482. 
  10. ^ Birch, Samuel J.; Boss, Sally R.; Cole, Sarah C.; Coles, Martyn P.; Haigh, Robert; Hitchcock, Peter B.; Wheatley, Andrew E. H. The structural characteristics of organozinc complexes incorporating N,N?-bidentate ligands. Dalton Transactions. 1 January 2004, (21): 3568–3574. PMID 15510278. doi:10.1039/B410945G. 
  11. ^ Kuhlmann, Matthias; Baumgartner, Thomas; Parvez, Masood. A new polymorph of dimesitylborinic acid. Acta Crystallographica Section E. 7 June 2008, 64 (7): o1185. PMC 2961869  . PMID 21202827. doi:10.1107/S1600536808015638. 
  12. ^ Weese, Kenneth J.; Bartlett, Ruth A.; Murray, Brendan D.; Olmstead, Marilyn M.; Power, Philip R. Synthesis and spectroscopic and structural characterization of derivatives of the quasi-alkoxide ligand [OBMes2]- (Mes = 2,4,6-Me3C6H2). Inorganic Chemistry. 1 July 1987, 26 (15): 2409–2413. doi:10.1021/ic00262a015. 
  13. ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始内容 (PDF)存档于2016-03-05）.  ref 28
  14. ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始内容 (PDF)存档于2016-03-05）.  ref 17
  15. ^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始内容 (PDF)存档于2016-03-05）.  ref 29
  16. ^ Winkle, D. boronic acids can be used as viable alternatives to borinic acids in suzuki coupling reactions. Organic Process Research & Development. 2001, 5 (4): 450–451. doi:10.1021/op010207s. [失效連結]
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