二(三苯基锡基)硫
化合物
二(三苯基锡基)硫是一种有机锡化合物，化学式为C36H30SSn2，或简写为(Ph3Sn)2S。它可由三苯基氯化锡和硫化钠反应制得。[2]在六羰基钼存在下，三苯基氢化锡和二甲基硫代甲酰胺反应，也能得到二(三苯基锡基)硫。[3]它可用于将羰基化合物转化为相应的硫羰基化合物。[4]
| 二(三苯基锡基)硫 | |
|---|---|
| |
| 别名 | 硫化三苯基锡 |
| 识别 | |
| CAS号 | 77-80-5 
|
| 性质 | |
| 化学式 | C36H30SSn2 |
| 摩尔质量 | 732.11 g·mol−1 |
| 熔点 | 141—143 °C（414—416 K）[1] |
| 相关物质 | |
| 相关化学品 | 六苯基二锡 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ "Metal-Organics Catalog" physical property data were obtained from Gelest, Inc. of Morrisville, Pennsylvania (US). Retrieved from SciFinder. [2022-11-27].
- ^ Marc Gingras, T. H. Chan, David N. Harpp. New methodologies: fluorodemetalation of organogermanium, -tin, and -lead compounds. Applications with organometallic sulfides to produce highly active anions and spectroscopic evidence for pentavalent intermediates in substitution at tin. The Journal of Organic Chemistry. 1990-03, 55 (7): 2078–2090 [2022-11-27]. ISSN 0022-3263. doi:10.1021/jo00294a021. （原始内容存档于2022-11-27） （英语）.
- ^ Renzo Arias-Ugarte, Hemant K. Sharma, Alejandro J. Metta-Magaña, Keith H. Pannell. Mo(CO) 6 -Catalyzed Reduction of N , N -Dimethylthioformamide by Silanes, Germanes, and Stannanes (R 3 EH) To Produce Trimethylamine and Group 14 Thioethers (R 3 E–S–ER 3 ). Organometallics. 2011-12-26, 30 (24): 6506–6509 [2022-11-27]. ISSN 0276-7333. doi:10.1021/om200753t. （原始内容存档于2022-11-27） （英语）.
- ^ K. Steliou, Mohamed Mrani. Reagents for organic synthesis. Tin-assisted sulfuration: a highly potent new method for the conversion of carbonyl units into their corresponding thiocarbonyl analogs. Journal of the American Chemical Society. 1982-06, 104 (11): 3104–3106 [2022-11-27]. ISSN 0002-7863. doi:10.1021/ja00375a027. （原始内容存档于2022-11-27） （英语）.