四氰合镍(II)酸锌

四氰合镍(II)酸锌是一种配位化合物,化学式为Zn[Ni(CN)4]。它可以和水或有机配体(如吡嗪[3])形成新的配合物。

四氰合镍(II)酸锌

英文名 zinc tetracyanonickelate(II)
识别
CAS号 41685-66-9  checkY
性质
化学式 C4N4NiZn
摩尔质量 228.17 g·mol−1
外观 黄色固体[1]或白色固体[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

制备

将可溶性镍盐加入至含[Zn(CN)4]2−的溶液中,会得到绿色的Ni[Zn(CN)4],由于[Ni(CN)4]2−(logβ4=31.3)比[Zn(CN)4]2−(logβ4=16.7)更稳定,它会迅速转化为黄色的Zn[Ni(CN)4]。[1][4]

直接以四氰合镍(II)酸钾一水合物和乙酸锌为原料反应,也能得到四氰合镍(II)酸锌。[5]

参考文献

  1. ^ 1.0 1.1 无机化学丛书 第六卷 卤素 铜分族 锌分族. 科学出版社. pp 714-715. (5) 氰化锌.
  2. ^ Rose, P. H. Action of bases on heavy-metal complex cyanides and the electromotive force series. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1954. 277: 205-208. ISSN: 0044-2313.
  3. ^ J. Rodríguez-Hernández, A.A. Lemus-Santana, J. Ortiz-López, S. Jiménez-Sandoval, E. Reguera. Low temperature structural transformation in T[Ni(CN)4]·xpyz with x=1,2; T=Mn,Co,Ni,Zn,Cd; pyz=pyrazine. Journal of Solid State Chemistry. 2010-01, 183 (1): 105–113 [2021-06-01]. doi:10.1016/j.jssc.2009.11.004. (原始内容存档于2020-02-12) (英语). 
  4. ^ Yunfeng Xu, Jia Zhang, Ying Liang, Jizhi Zhou, Jun Zhao, Xiuxiu Ruan, Zhi Ping Xu, Guangren Qian. Synchronous cyanide purification with metals removal in the co-treatment of Zn–CN and Ni electroplating wastewaters via the Ni2+-assisted precipitation of LDH. Separation and Purification Technology. 2015-05, 145: 92–97 [2021-06-01]. doi:10.1016/j.seppur.2015.02.040 (英语). 
  5. ^ Zeki Kartal, Onur Şahi̇N, Abdülkerim Yavuz. Synthesis of Hofmann-type Zn(H2O)2Ni(CN)4.nG (G = water and 1,4-dioxane)clathrates and the determination of their structural properties by variousspectroscopic methods. TURKISH JOURNAL OF CHEMISTRY. 2019-12-09, 43 (6): 1608–1621 [2021-06-01]. doi:10.3906/kim-1906-26. [失效連結]