氧氮化物

氧氮化物是一类无机化合物,其中原子和原子不互相连接,它们分别和另一金属或非金属元素相连,如氧氮化铝英语Aluminium oxynitride。氮氧化物也可以形成阴离子(氮杂氧酸盐),如氮基锇酸钾俄语Нитридотриоксоосмат(VIII) калия,在其阴离子中,氮和氧分别与原子相连,而它们之间并不成键。[2]

氧氮化铝的结构,其中橙色表示Al3+,红色表示O2−/N3−。它的商品名是ALON。[1]

相比于氧化物,氧氮化物的带隙更小。[3]

参考文献

  1. ^ Richard L. Gentilman et al. Transparent aluminum oxynitride and method of manufacture U.S. Patent 4,520,116 Issue date: May 28, 1985
  2. ^ Справочник химика 1 2-е изд., испр. М.-Л.: Химия. Редкол.: Никольский Б.П. и др. 1966 (俄语). 
  3. ^ Ya Tang, Kosaku Kato, Takayoshi Oshima, Hiroto Mogi, Akinobu Miyoshi, Kotaro Fujii, Kei-ichi Yanagisawa, Koji Kimoto, Akira Yamakata, Masatomo Yashima, Kazuhiko Maeda. Synthesis of Three-Layer Perovskite Oxynitride K 2 Ca 2 Ta 3 O 9 N·2H 2 O and Photocatalytic Activity for H 2 Evolution under Visible Light. Inorganic Chemistry. 2020-08-03, 59 (15): 11122–11128 [2022-05-29]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.0c01607. (原始内容存档于2022-05-29) (英语).