1,3,5-苯三甲醛

化合物

1,3,5-苯三甲醛是一种有机化合物,化学式为C9H6O3。它可由均苯三甲酸酯化后经氢化铝锂还原、氯铬酸吡啶氧化制得。[2]它和丙二腈在催化下反应,可以得到1,3,5-三(2,2-二氰基乙烯基)苯。[3]

1,3,5-苯三甲醛
别名 1,3,5-三甲酰基苯
识别
CAS号 3163-76-6  checkY
SMILES
 
  • O=CC=1C=C(C=O)C=C(C=O)C1
性质
化学式 C9H6O3
摩尔质量 162.14 g·mol−1
熔点 160 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ AL-Saleh, Balkis; Makhseed, Saad; Hassaneen, Huwaida M.; Elnagdi, Mohamed Hilmy (2006). Studies with Functionally Substituted Enamines: The Reactivity of Enaminals and Enamino Esters toward Naphthoquinone, Hydrazonoyl Halides, Aminoazoles and Hippuric Acid. Synthesis, 2006(1), 59–62. doi:10.1055/s-2005-921750.
  2. ^ Linyi Bai; et al. Nanoscale covalent organic frameworks as smart carriers for drug delivery. Chem. Commun., 2016, 52, 4128-4131. doi:10.1039/C6CC00853D.
  3. ^ Kai-Yu Cheng, Shi-Cheng Wang, Yu-Sheng Chen, and Yi-Tsu Chan. Self-Assembly and Catalytic Reactivity of BINOL-Bridged Bis(phenanthroline) Metallocages. Inorg. Chem. 2018, 57, 7, 3559–3567. doi:10.1021/acs.inorgchem.7b02540.