1,4-二乙烯基苯
1,4-二乙烯基苯是一种有机化合物,化学式为C10H10。它可由1,4-二(溴甲基)苯和甲醛在碳酸钾和三苯基膦的存在下反应得到。[3]其它制法还包括1,4-二苯甲醛和三苯基亚甲基磷的反应[4]、1,4-二碘苯和三乙烯基铟的反应[5]、1,4-二乙炔基苯的加氢反应[6]1,4-二乙苯的脱氢反应[7]等。
1,4-二乙烯基苯 | |
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别名 | 1,4-二乙烯苯 |
识别 | |
CAS号 | 105-06-6 ![]() |
性质 | |
化学式 | C10H10 |
摩尔质量 | 130.19 g·mol−1 |
密度 | 1.5805 g·cm−3(20 °C)[1] 0.913 g·cm−3(40 °C)[2] |
熔点 | 31 °C(304 K)[2] |
沸点 | 52 °C(325 K)(4 torr)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Yakovich, N. I.; Khcheyan, Kh. E.; Pavlichev, A. F.; Kondrat'eva, N. N.; Izrael, L. B. High-purity divinylbenzenes. 1969. GB 1149475.
- ^ 2.0 2.1 2.2 Lespieau; Deluchat. p-Divinylbenzene and p-diacetenylbenzene. Compt. rend., 1930. 190: 683-684.
- ^ Jiang, Min; Yang, Haijun; Lefebvre, Quentin; Su, Jihu; Fu, Hua. Olefination of Alkyl Halides with Aldehydes by Merging Visible-Light Photoredox Catalysis and Organophosphorus Chemistry. iScience. 2018, 6: 102–113. ISSN 2589-0042. doi:10.1016/j.isci.2018.07.011.
- ^ Monika Ludwiczak, Mariusz Majchrzak, Bogdan Marciniec, Maciej Kubicki. Highly stereoselective synthesis of novel trans-thiophenylene-silylene-vinylene-arylene molecular and macromolecular compounds. Journal of Organometallic Chemistry. 2011-04, 696 (7): 1456–1464 [2021-06-30]. doi:10.1016/j.jorganchem.2011.01.020. (原始内容存档于2020-02-25) (英语).
- ^ Miguel A. Pena, José Pérez Sestelo, Luis A. Sarandeses. New Synthetic Applications of Indium Organometallics in Cross-Coupling Reactions. Synthesis. 2005, 2005 (03): 485–492 [2021-06-30]. ISSN 0039-7881. doi:10.1055/s-2004-834945. (原始内容存档于2018-06-03) (德语).
- ^ Wienhöfer, Gerrit; Westerhaus, Felix A.; Jagadeesh, Rajenahally V.; Junge, Kathrin; Junge, Henrik; Beller, Matthias. Selective iron-catalyzed transfer hydrogenation of terminal alkynes. Chemical Communications. 2012, 48 (40): 4827. ISSN 1359-7345. doi:10.1039/c2cc31091k.
- ^ Bachmann, Reinhard; Siekiera, Karl Heinz; Wegewitz, Kurt; Feldhaus, Reinhard; Vieweg, Hans Guenther; Schoenfeld, Dieter; Zielke, Erich; Anders, Klaus. Preparation of divinylbenzene by dehydrogenation of diethylbenzene(德文). 1990. DD 282815 A7.