2-氰基-3-(4-硝基苯基)丙烯酸甲酯
化合物
2-氰基-3-(4-硝基苯基)丙烯酸甲酯是一种有机化合物，化学式为C11H8N2O4。它可由4-硝基苯甲醛和氰乙酸甲酯在哌啶催化下于甲醇中反应得到。[3]它和氯气发生加成反应，得到α,β-二氯-α-氰基-4-硝基苯丙酸甲酯。[4]
| 2-氰基-3-(4-硝基苯基)丙烯酸甲酯 | |
|---|---|
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| 别名 | α-氰基对硝基肉桂酸甲酯 |
| 识别 | |
| CAS号 | 62985-31-3  42348-04-9（2E） 14479-59-5（Z）
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| 性质 | |
| 化学式 | C11H8N2O4 |
| 摩尔质量 | 232.19 g·mol⁻¹ |
| 熔点 | 172—173 °C（445—446 K）[1] 178 °C（451 K）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ Lange, J.; Rump, S.; Galecka, E.; Ilczuk, I.; Lechowska-Postek, M.; Rabsztyn, T.; Szymanska, T.; Walczyna, K. Synthesis and properties of new cyclic derivatives of succinic acid with anticonvulsant activity. Pharmazie, 1977. 32 (2): 82-84. ISSN: 0031-7144.
- ^ Saeed Balalaie, Morteza Bararjanian, Shohreh Hekmat, Peyman Salehi. Novel, Efficient, and Green Procedure for the Knoevenagel Condensation Catalyzed by Diammonium Hydrogen Phosphate in Water. Synthetic Communications. 2006-08-01, 36 (17): 2549–2557 [2021-05-17]. ISSN 0039-7911. doi:10.1080/00397910600781471 （英语）.
- ^ Katie M. Herbert, Patrick T. Getty, Neil D. Dolinski, Jerald E. Hertzog, Derek de Jong, James H. Lettow, Joy Romulus, Jonathan W. Onorato, Elizabeth M. Foster, Stuart J. Rowan. Dynamic reaction-induced phase separation in tunable, adaptive covalent networks. Chemical Science. 2020, 11 (19): 5028–5036 [2021-05-17]. ISSN 2041-6520. doi:10.1039/D0SC00605J （英语）.
- ^ Zvi Rappoport, Bianca Avramovitch. Nucleophilic attacks on carbon-carbon double bonds. 28. Complete and partial stereoconversion in the substitution of methyl (E)- and (Z)-.beta.-chloro-.alpha.-cyano-p-nitrocinnamates by nucleophiles. The Journal of Organic Chemistry. 1982-04, 47 (8): 1397–1408 [2021-05-17]. ISSN 0022-3263. doi:10.1021/jo00347a003 （英语）.