2-硝基溴苯

化合物

2-硝基溴苯是一种有机化合物,化学式为C6H4BrNO2。它可以在溴苯的硝化反应中生成,但并非主产物。[3][4]2-硝基苯胺重氮化-溴化反应[5]以及2-溴苯胺的氧化反应[6]可以以较高产率得到2-硝基溴苯。

2-硝基溴苯
识别
CAS号 577-19-5  checkY
SMILES
 
  • Brc1ccccc1[N+](=O)[O-]
性质
化学式 C6H4BrNO2
摩尔质量 202.01 g·mol⁻¹
熔点 41—42 °C(314—315 K)[1]
沸点 258—265 °C(531—538 K)[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Robert A. Benkeser, Philip E. Brumfield. Nitration of Organosilicon Compounds with Copper Nitrate. Journal of the American Chemical Society. 1951-10, 73 (10): 4770–4773 [2021-05-19]. ISSN 0002-7863. doi:10.1021/ja01154a087 (英语). 
  2. ^ Inagaki, Sigenobu. Diphenylisatin and its derivatives. IV. Monobromo derivatives of dianisoleisatin and its oxidation product. Yakugaku Zasshi, 1938. 58: 961-975. ISSN: 0031-6903.
  3. ^ Radoslaw R Bak, Andrew J Smallridge. A fast and mild method for the nitration of aromatic rings. Tetrahedron Letters. 2001-09, 42 (38): 6767–6769 [2021-05-19]. doi:10.1016/S0040-4039(01)01378-8. (原始内容存档于2020-11-06) (英语). 
  4. ^ Christopher G Frost, Joseph P Hartley, David Griffin. Counterion effects in indium-catalysed aromatic electrophilic substitution reactions. Tetrahedron Letters. 2002-07, 43 (27): 4789–4791 [2021-05-19]. doi:10.1016/S0040-4039(02)00931-0. (原始内容存档于2018-07-01) (英语). 
  5. ^ Woonphil Baik, Wanqiang Luan, Hyun Joo Lee, Cheol Hun Yoon, Sangho Koo, Byeong Hyo Kim. Efficient one-pot transformation of aminoarenes to haloarenes using halodimethylisulfonium halides generated in situ. Canadian Journal of Chemistry. 2005-03-01, 83 (3): 213–219 [2021-05-19]. ISSN 0008-4042. doi:10.1139/v05-026 (英语). 
  6. ^ Jia Liu, Jue Li, Jiangmeng Ren, Bu-Bing Zeng. Oxidation of aromatic amines into nitroarenes with m-CPBA. Tetrahedron Letters. 2014-02, 55 (9): 1581–1584 [2021-05-19]. doi:10.1016/j.tetlet.2014.01.073. (原始内容存档于2018-06-10) (英语).