2-碘苯胺
化合物
2-碘苯胺是一种有机化合物，化学式为C6H6IN。它可由2-硝基碘苯在催化下被氢气[3]或水合肼[4]还原得到。它也可由2-氨基苯硼酸和碘化钠在通电（10 mA）条件下反应制得。[1]它和苯乙炔在碘化亚铜、二氯双(三苯基膦)钯催化下于三乙胺中反应，可以得到2-苯乙炔基苯胺。[5]
| 2-碘苯胺 | |
|---|---|
| |
| 别名 | 2-氨基碘苯 |
| 识别 | |
| CAS号 | 615-43-0 
|
| 性质 | |
| 化学式 | C6H6IN |
| 摩尔质量 | 219.02 g·mol−1 |
| 外观 | 黄色固体[1] |
| 熔点 | 56—58 °C（329—331 K）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 Zhengjiang Fu, Guangguo Hao, Yaping Fu, Dongdong He, Xun Tuo, Shengmei Guo, Hu Cai. Transition metal-free electrocatalytic halodeborylation of arylboronic acids with metal halides MX (X = I, Br) to synthesize aryl halides. Organic Chemistry Frontiers. 2020, 7 (3): 590–595 [2023-04-06]. ISSN 2052-4129. doi:10.1039/C9QO01139K （英语）.
- ^ Surya Srinivas Kotha, Nidhi Sharma, Govindasamy Sekar. Stable and reusable platinum nanocatalyst: an efficient chemoselective reduction of nitroarenes in water. Tetrahedron Letters. 2016-03, 57 (13): 1410–1413 [2023-04-06]. doi:10.1016/j.tetlet.2016.01.111. （原始内容存档于2018-06-28） （英语）.
- ^ Wenjun Yu, Lan-Lan Lou, Shanshan Li, Tianyuan Ma, Lezi Ouyang, Li Feng, Shuangxi Liu. Highly efficient and durable platinum nanocatalysts stabilized by thiol-terminated poly(N-isopropyl acrylomide) for selective hydrogenation of halonitrobenzene to haloaniline. RSC Advances. 2017, 7 (2): 751–757 [2023-04-06]. ISSN 2046-2069. doi:10.1039/C6RA24773C （英语）.
- ^ Velu Sadhasivam, Mathappan Mariyappan, Ayyanar Siva. Porous Triazine Containing Covalent Organic Polymer Supported Pd Nanoparticles: A Stable and Efficient Heterogeneous Catalyst for Sonogashira Cross-Coupling and the Reduction of Nitroarenes. ChemistrySelect. 2018-12-19, 3 (47): 13442–13455 [2023-04-06]. doi:10.1002/slct.201802977 （英语）.
- ^ Álvaro González-Gómez, Gema Domínguez, Javier Pérez-Castells. Synthesis of Benzazepines by Gold-Catalysed Reactions of N -Allenylamides. European Journal of Organic Chemistry. 2009-10, 2009 (29): 5057–5062 [2023-04-06]. doi:10.1002/ejoc.200900745 （英语）.