MIL-53是一种金属有机框架材料,名称中字母缩写MIL为Matériaux de l′Institut Lavoisier,它由圣康丁昂伊夫利纳-凡尔赛大学拉瓦锡研究所的Gérard Férey组所合成。[1]目前已知其它三价金属的类似物,如Al[2]、Fe[3]等。不同种类的MIL-53材料按下述区分:MIL-53asas = as synthesized(合成原态),使用了对苯二甲酸)、MIL-53ltlt = low temperature(低温),低温改性)和MIL-53htht = high temperature(高温),高温改性)。

MIL-53
别名 MIL-53(Cr)
识别
缩写 MIL-53(Cr)
CAS号 442912-79-0(无水)  checkY
477890-83-8(一水合物)  checkY
477890-84-9(一DMF合物)  checkY
性质
化学式 C8H5CrO5
外观 固体
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Serre, Christian; Millange, Franck; Thouvenot, Christelle; Noguès, Marc; Marsolier, Gérard; Louër, Daniel; Férey, Gérard. Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or Cr III (OH)·{O 2 C−C 6 H 4 −CO 2 }·{HO 2 C−C 6 H 4 −CO 2 H} x ·H 2 O y. Journal of the American Chemical Society. 2002-11-01, 124 (45). ISSN 0002-7863. doi:10.1021/ja0276974 (英语). 
  2. ^ Loiseau, Thierry; Serre, Christian; Huguenard, Clarisse; Fink, Gerhard; Taulelle, Francis; Henry, Marc; Bataille, Thierry; Férey, Gérard. A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration. Chemistry - A European Journal. 2004-03-19, 10 (6). ISSN 0947-6539. doi:10.1002/chem.200305413 (英语). 
  3. ^ Horcajada, Patricia; Serre, Christian; Maurin, Guillaume; Ramsahye, Naseem A.; Balas, Francisco; Vallet-Regí, María; Sebban, Muriel; Taulelle, Francis; Férey, Gérard. Flexible Porous Metal-Organic Frameworks for a Controlled Drug Delivery. Journal of the American Chemical Society. 2008-05-01, 130 (21) [2022-10-01]. ISSN 0002-7863. doi:10.1021/ja710973k. (原始内容存档于2022-10-06) (英语). 

参见