甲胺氢碘酸盐
甲胺氢碘酸盐是一种有机盐，化学式为CH3NH3I。它可由甲胺和氢碘酸在冰水溶液（或甲醇水溶液[2]）中反应得到，蒸去溶剂得到晶体。[3]它和碘化铅在γ-丁内酯中于60 °C反应，可以得到CH3NH3PbI3。[2]
| 甲胺氢碘酸盐 | |||
|---|---|---|---|
| |||
| IUPAC名 Methylazanium iodide | |||
| 系统名 Methanaminium iodide | |||
| 别名 | 碘化甲铵 | ||
| 识别 | |||
| CAS号 | 14965-49-2 
| ||
| PubChem | 519034 | ||
| ChemSpider | 452756 | ||
| SMILES |
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| EINECS | 239-037-4 | ||
| 性质 | |||
| 化学式 | CH3NH3I | ||
| 摩尔质量 | 158.969 g·mol⁻¹ | ||
| 外观 | 白色粉末 | ||
| 熔点 | 263—265 °C（536—538 K）[1] | ||
| 危险性 | |||
GHS危险性符号
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| GHS提示词 | 警告 | ||
| H-术语 | H302, H315, H319, H335 | ||
| P-术语 | P261, P264, P270, P271, P280, P301+312, P302+352, P304+340, P305+351+338, P312, P321, P330, P332+313, P337+313 | ||
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |||
参考文献
- ^ Biltz, Heinrich; Max, Fritz. Chemistry of uric acid. XVI. Methylammonium iodide. Justus Liebigs Annalen der Chemie,1921. 423: 296-300. ISSN: 0075-4617.
- ^ 2.0 2.1 Hua-Rong Xia, Jia Li, Wen-Tao Sun, Lian-Mao Peng. Organohalide lead perovskite based photodetectors with much enhanced performance. Chem. Commun. 2014, 50 (89): 13695–13697 [2021-03-13]. ISSN 1359-7345. doi:10.1039/C4CC05960C （英语）.
- ^ Jeffrey A. Christians, Raymond C. M. Fung, Prashant V. Kamat. An Inorganic Hole Conductor for Organo-Lead Halide Perovskite Solar Cells. Improved Hole Conductivity with Copper Iodide. Journal of the American Chemical Society. 2014-01-15, 136 (2): 758–764 [2021-03-13]. ISSN 0002-7863. doi:10.1021/ja411014k. （原始内容存档于2021-01-30） （英语）.