2-噻吩甲酸
化合物
2-噻吩甲酸是一種有機化合物，化學式為SC4H3CO2H。它和噻吩-3-羧酸是噻吩的兩種單羧酸。[1]2-噻吩甲酸亞銅是烏爾曼反應的催化劑。
| 2-噻吩甲酸 | |
|---|---|
| |
| 識別 | |
| CAS號 | 527-72-0 
|
| PubChem | 10700 |
| ChemSpider | 10250 |
| SMILES |
|
| EINECS | 208-423-4 |
| ChEBI | 71241 |
| KEGG | D08568 |
| 性質 | |
| 化學式 | C5H4O2S |
| 摩爾質量 | 128.15 g·mol−1 |
| 外觀 | 白色固體 |
| 熔點 | 125-127 °C（398-400 K） |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
合成
應用和反應
參考文獻
- ^ E. Campaigne, William M. LeSuer. 3-Thenoic Acid. Organic Syntheses. 1953, 33: 94. doi:10.15227/orgsyn.033.0094.
- ^ 2.0 2.1 Swanston, Jonathan. Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. 2006. ISBN 3527306730. doi:10.1002/14356007.a26_793.pub2..
- ^ Knight, David W.; Nott, Andrew P. Generation and Synthetic Utility of Dianions Derived from Thiophenecarboxylic Acids. Journal of the Chemical Society, Perkin Transactions 1. 1983: 791-4. doi:10.1039/p19830000791.
- ^ Gooßen, Lukas J.; Deng, Guojun; Levy, Laura M. Synthesis of Biaryls via Catalytic Decarboxylative Coupling. Science. 2006, 313 (5787): 662–664. Bibcode:2006Sci...313..662G. PMID 16888137. S2CID 1781760. doi:10.1126/science.1128684.
- ^ Rakshit, Souvik; Grohmann, Christoph; Besset, Tatiana; Glorius, Frank. Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile. Journal of the American Chemical Society. 2011, 133 (8): 2350–2353. PMID 21275421. doi:10.1021/ja109676d.