甲基丙烯酸乙酯
化合物
甲基丙烯酸乙酯是一种有机化合物，化学式为C2H5O2CC(CH3)=CH2。它是无色液体，是制备丙烯酸酯聚合物的常见单体。[2]它可由甲基丙烯酸和乙醇的酯化反应制得。[3]它在自由基条件下可以聚合。[4]
| 甲基丙烯酸乙酯 | |
|---|---|
| |
| 识别 | |
| CAS号 | 97-63-2 
|
| PubChem | 7343 |
| ChemSpider | 7066 |
| SMILES |
|
| UN编号 | 2277 |
| RTECS | OZ4550000 |
| 性质 | |
| 化学式 | C6H10O2 |
| 摩尔质量 | 114.14 g·mol−1 |
| 外观 | 无色液体 |
| 密度 | 0.9135 g/cm3[1] |
| 熔点 | ＞−75 °C[1] |
| 沸点 | 117 °C（390 K）[1] |
| 危险性 | |
GHS危险性符号 
| |
| GHS提示词 | 警告 |
| H-术语 | H225, H315, H317, H319, H335 |
| P-术语 | P210, P233, P240, P241, P242, P243, P261, P264, P271, P272, P280, P302+352, P303+361+353, P304+340 |
| NFPA 704 |
 3
2
2
|
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 1.2 "Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2020-08-26]
- ^ Bauer, Jr., William, Methacrylic Acid and Derivatives, Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, 2005, doi:10.1002/14356007.a16_441.
- ^ Mirosław Grzesik, Teresa Witczak. The influence of the catalyst on the kinetics of ethyl metacrylate synthesis. Polish Journal of Chemical Technology. 2007-01-01, 9 (1): 7–9 [2020-08-25]. ISSN 1899-4741. doi:10.2478/v10026-007-0003-1.
- ^ Granel, C.; Dubois, Ph.; Jérôme, R.; Teyssié, Ph. Controlled Radical Polymerization of Methacrylic Monomers in the Presence of a Bis(ortho-chelated) Arylnickel(II) Complex and Different Activated Alkyl Halides. Macromolecules. 1996, 29 (27): 8576–8582. Bibcode:1996MaMol..29.8576G. doi:10.1021/ma9608380.