硫代钨酸盐
常见的硫代钨酸盐
| 化合物 | CAS号 | 性质 | 参考文献 |
|---|---|---|---|
| 四硫代钨酸钾 K2WS4 |
|||
| 四硫代钨酸铷 Rb2WS4 |
黄色固体，a=9.69 Å,b=7.10 Å,c=12.45 Å | [1] | |
| 四硫代钨酸铯 Cs2WS4 |
[2] | ||
| 四硫代钨酸铵 (NH4)2WS4 |
13862-78-7 | ||
| 四硫代钨酸四苯基𬭸 (PPh4)2WS4 |
和卤代烃反应： (PPh4)2WS4 + RX → (PPh4)[WS3(RS)] + PPh4X |
[3] | |
| 四硫代钨酸哌啶𬭩 (C5H10NH2)2WS4 |
硫代钨酸根配合物
WS2−
4可以作为配体和其它过渡金属离子形成配阴离子，如[Co(WS4)2]2−、[Ni(WS4)2]2−[4]、[WO(WS4)2]2−[5]等。
参考文献
- ^ Yao J, Ibers J A. Dirubidium tetrathiotungstate, Rb2WS4[J]. Acta Crystallographica, 2004, 60(2):i10-i11.
- ^ Srinivasan B R, Näther C, Bensch W. Dicaesium tetrathiotungstate(VI)[J]. Acta Crystallographica, 2007, 63:i167.
- ^ Lang J P, Kawaguchi H, Tatsumi K. Reactions of tetrathiotungstate and tetrathiomolybdate with substituted haloalkanes[J]. Journal of the Chemical Society Dalton Transactions, 2002, 43(12):2573-2580.
- ^ Crossland C J, Evans I R, Evans J S. Structural chemistry of (PPh4)2M(WS4)2 materials[J]. Dalton Transactions, 2008, 12(12):1597-1601.
- ^ Francis Secheresse, Guy Lavigne, Yves Jeannin,等. SYNTHESIS AND MOLECULAR STRUCTURE OF BIS(TETRATHIOTUNGSTATO(VI)-S,S′) OXOTUNGSTATE(IV), ((C6H5)4P)2(WO(WS4)2)−2[J]. Journal of Coordination Chemistry, 1981, 11(1):11-16.