苯乙炔亞銅

苯乙炔亞銅是一種有機銅化合物,化學式為{C8H5Cu}n。它可由苯乙炔和二氨合銅(I)鹽反應製得。[1]它可以和三乙基膦反應,得到(C2H5)3PCuC≡CPh(Ph=C6H5)。[2]它和一種膦配體L(L=Ph2PCH2(CH2OCH2)2CH2PPh2)反應,可以得到亮黃色的Cu4(C≡CPh)4L2[3]

苯乙炔亞銅
識別
CAS號 13146-23-1  checkY
性質
化學式 C8H5Cu
摩爾質量 164.67 g·mol−1
外觀 黃色固體[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ 1.0 1.1 SUBSTITUTION OF ARYL HALIDES WITH COPPER(I) ACETYLIDES: 2-PHENYLFURO[3,2-b]PYRIDINE. Organic Syntheses (Organic Syntheses). 1972, 52: 128. ISSN 0078-6209. doi:10.15227/orgsyn.052.0128. 
  2. ^ Blake, D.; Calvin, G.; Coates, G. E. Copper and silver ethynyl coördination complexes. Proceedings of the Chemical Society, London, 1959: 396-397. ISSN 0369-8718.
  3. ^ Chan, Wing-Han; Zhang, Zheng-Zhi; Mak, Thomas C.W; Che, Chi-Ming. A highly luminescent tetranuclear copper(I) cluster: structure and photophysical properties. Journal of Organometallic Chemistry (Elsevier BV). 1998, 556 (1-2): 169–172. ISSN 0022-328X. doi:10.1016/s0022-328x(97)00702-x.