正丁基鈉
正丁基鈉是一種有機鈉化合物，化學式為C4H9Na，它具有強鹼性，為聚合結構。它可由正丁基鋰和叔丁醇鈉反應製得。[2]它和1-溴萘反應，可以得到1-溴丁烷和1-萘基鈉。[3]
| 正丁基鈉 | |
|---|---|
| |
| IUPAC名 | |
| 別名 | 丁基鈉 |
| 識別 | |
| CAS號 | 3525-44-8 
|
| PubChem | 101040259 |
| ChemSpider | 11351318 |
| SMILES |
|
| InChI |
|
| InChIKey | IRDQNLLVRXMERV-UHFFFAOYSA-N |
| 性質 | |
| 化學式 | C4H9Na |
| 摩爾質量 | 80.1 g·mol−1 |
| 外觀 | 白色固體[1] |
| 危險性 | |
GHS危險性符號 
| |
| GHS提示詞 | 危險 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
- ^ Martinez-Martinez, A. J.; Kennedy, A. R.; Mulvey, R. E.; O'Hara, C. T. Supplementary Material for Directed ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonation. Science. 13 November 2014, 346 (6211): 834–837 [2024-09-10]. Bibcode:2014Sci...346..834M. PMID 25395533. S2CID 206561570. doi:10.1126/science.1259662. （原始內容存檔於2022-04-30）.
- ^ Schade, Christian; Bauer, Walter; Von Ragué Schleyer, Paul (November 1985). "n-Butylsodium: The preparation, properties and NMR spectra of a hydrocarbon- and tetrahydrofuran-soluble reagent". Journal of Organometallic Chemistry. 295 (3): c25–c28. doi:10.1016/0022-328X(85)80326-0
- ^ Gilman, Henry; Moore, Fred W.; Baine, Ogden (September 1941). "Secondary and Tertiary Alkyllithium Compounds and Some Interconversion Reactions with Them". Journal of the American Chemical Society. 63 (9): 2479–2482. doi:10.1021/ja01854a046