溴碘甲烷
化合物
溴碘甲烷 | |
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IUPAC名 Bromoiodomethane | |
識別 | |
CAS號 | 557-68-6 |
PubChem | 68407 |
ChemSpider | 61690 |
SMILES |
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InChI |
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性質 | |
化學式 | CH2BrI |
摩爾質量 | 220.84 g/mol g·mol⁻¹ |
外觀 | 液體 |
密度 | 2.926 g/cm3(17 °C) |
熔點 | 1 °C |
沸點 | 139.5 °C |
危險性 | |
警示術語 | R:R37/38 R41 |
安全術語 | S:S26 S36/39 |
歐盟分類 | 刺激性 (Xi) |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
它的臨界點為367.85 °C和6.3 MPa,折射率為1.6382 (20 °C, D)。
參考文獻
- Tarnovsky A. N., Wall M., Gustafsson M., Lascoux N., Sundström V., Åkesson E. Ultrafast Study of the Photodissociation of Bromoiodomethane in Acetonitrile upon 266 nm Excitation. J. Phys. Chem. A. March 2002, 106 (25): 5999–6005(7) [2007-06-29]. doi:10.1021/jp014306j. (原始內容存檔於2007-09-29).
- Liu Y.-J., Ajitha D., Krogh J. W., Tarnovsky A. N., Lindh R. Spin-Orbit Ab Initio Investigation of the Photolysis of Bromoiodomethane. ChemPhysChem. December 2005, 7 (4): 955–963(9) [2007-06-29]. PMID 16596616. doi:10.1002/cphc.200500654. (原始內容存檔於2011-08-13).
- Zheng, X.; Phillips, D. L. Photoisomerization reaction of CH2BrI following A-band and B-band photoexcitation in the solution phase: Transient resonance Raman observation of the iso-CH2I-Br photoproduct. J. Chem. Phys. August 2000, 113 (8): 3194–3203(10). Bibcode:2000JChPh.113.3194Z. doi:10.1063/1.1286920.
- Liu K., Zhao H., Wang C., Zhang A., Ma S., Li Z. A theoretical study of bond selective photochemistry in CH2BrI. J. Chem. Phys. January 2005, 122 (4): 044310 [2007-06-29]. PMID 15740251. doi:10.1063/1.1835955.