4-碘苯甲腈

化合物

4-碘苯甲腈是一種有機化合物,化學式為C7H4IN。它可由4-碘苯甲醛DMPU鹽酸鹽的存在下和鹽酸羥胺反應製得,[2]或由4-氰基苯胺亞硝酸叔丁酯反應得到。[3]它和苯硼酸在鈀催化劑和(如碳酸鉀)存在下反應,可以得到4-氰基聯苯[4]

4-碘苯甲腈
別名 對碘苯甲腈
4-氰基碘苯
對氰基碘苯
識別
CAS號 3058-39-7  checkY
性質
化學式 C7H4IN
摩爾質量 229.02 g·mol−1
熔點 123—125 °C(396—398 K)[1]
相關物質
其他陰離子 4-氟苯甲腈德語4-Fluorbenzonitril
4-氯苯甲腈
4-溴苯甲腈
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ Amin Zarei, Abdol Hajipour, Leila Khazdooz. A One-Pot Method for the Iodination of Aryl Amines via Stable Aryl Diazonium Silica Sulfates Under Solvent-Free Conditions. Synthesis. 2009-03-02, 2009 (06): 941–944 [2021-12-22]. ISSN 0039-7881. doi:10.1055/s-0028-1087981. (原始內容存檔於2018-06-03) (英語). 
  2. ^ Mudshinge, Sagar R.; Potnis, Chinmay S.; Xu, Bo; Hammond, Gerald B. HCl·DMPU-assisted one-pot and metal-free conversion of aldehydes to nitriles. Green Chemistry (Royal Society of Chemistry (RSC)). 2020, 22 (13): 4161–4164. ISSN 1463-9262. doi:10.1039/d0gc00757a. 
  3. ^ Malet-Sanz, Laia; Madrzak, Julia; Holvey, Rhian S.; Underwood, Toby. A safe and reliable procedure for the iododeamination of aromatic and heteroaromatic amines in a continuous flow reactor. Tetrahedron Letters (Elsevier BV). 2009, 50 (52): 7263–7267. ISSN 0040-4039. doi:10.1016/j.tetlet.2009.10.007. 
  4. ^ Eskedar Tessema, Vijayanath Elakkat, Chiao-Fan Chiu, Zong-Lin Tsai, Ka Long Chan, Chia-Rui Shen, Han-Chang Su, Norman Lu. Recoverable Palladium-Catalyzed Carbon-Carbon Bond Forming Reactions under Thermomorphic Mode: Stille and Suzuki-Miyaura Reactions. Molecules. 2021-03-05, 26 (5): 1414 [2021-12-22]. ISSN 1420-3049. doi:10.3390/molecules26051414. (原始內容存檔於2021-12-22) (英語).