二異丙基鋅
化合物
二異丙基鋅 是一種有機鋅化合物 ,化學式 ZnC6H14。[2]它可由鋅粉和2-碘丙烷在200 °C反應製得;[1]或者由2-溴丙烷和鎂反應製得格氏試劑異丙基溴化鎂,再在乙醚中和溴化鋅反應得到。[3]
二異丙基鋅 | |
---|---|
![]() | |
![]() | |
識別 | |
CAS號 | 625-81-0 ![]() |
PubChem | 5207587 |
ChemSpider | 11347073 |
SMILES |
|
InChI |
|
InChIKey | KDUNMLRPPVCIGP-LSPCJBSIAV |
性質 | |
化學式 | C6H14Zn |
摩爾質量 | 151.56 g·mol⁻¹ |
沸點 | 300 °C(573 K)(分解)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考資料
- ^ 1.0 1.1 Pochekutova, T. S.; Khamylov, V. K.; Domrachev, G. A.; Zhuk, B. V. Direct synthesis of dipropyl- and diisopropylzinc. Zhurnal Organicheskoi Khimii, 1987. 23 (10): 2156-2160. ISSN: 0514-7492.
- ^ Benjamin Bederson; Herbert Walther. Advances in Atomic, Molecular, and Optical Physics. Gulf Professional Publishing. 2002: 250– [2013-08-06]. ISBN 978-0-12-003848-0. (原始內容存檔於2016-05-09).
- ^ Eike Hupe, M. Isabel Calaza, Paul Knochel. Substrate-Controlled Highly Diastereoselective Synthesis of Primary and Secondary Diorganozinc Reagents by a Hydroboration/Boron–Zinc Exchange Sequence. Chemistry - A European Journal. 2003-06-16, 9 (12): 2789–2796 [2020-12-07]. doi:10.1002/chem.200204662.
- ^ Shibata, Takanori; Morioka, Hiroshi; Hayase, Tadakatsu; Choji, Kaori; Soai, Kenso. Highly Enantioselective Catalytic Asymmetric Automultiplication of Chiral Pyrimidyl Alcohol. Journal of the American Chemical Society. 1996, 118: 471. doi:10.1021/ja953066g.
這是一篇關於有機化合物的小作品。您可以透過編輯或修訂擴充其內容。 |