氧化膦
氧化膦是一種無機化合物,化學式為H3PO,它只在稀釋的氣相中穩定,而在液相或固相時不穩定。[1]它作為磷化氫和氧氣反應的產物通過質譜檢測得到。[2]它也是一氧化氮和磷化氫在室溫反應,生成PxHy固體的中間體。[3]
氧化膦 | |
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識別 | |
CAS號 | 13840-40-9 |
PubChem | 57448882 |
SMILES |
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性質 | |
化學式 | H3OP |
摩爾質量 | 50 g·mol−1 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
- ^ Greenwood, Norman Neill; Earnshaw, Alan. Chemistry of the elements. 2016. ISBN 978-0-7506-3365-9. OCLC 1040112384 (英語).
- ^ Hamilton, Peter A.; Murrells, Timothy P. Kinetics and mechanism of the reactions of PH3 with O(3P) and N(4S) atoms. J. Chem. Soc., Faraday Trans. 1985, 2 (81): 1531–1541. doi:10.1039/F29858101531.
- ^ Zhao, Yi-Lei; Flora, Jason W.; David Thweatt, William; Garrison, Stephen L.; Gonzalez, Carlos; Houk, K. N.; Marquez, Manuel. Phosphine Polymerization by Nitric Oxide: Experimental Characterization and Theoretical Predictions of Mechanism. Inorg. Chem. 2009, 48 (3): 1223–1231. PMID 19102679. doi:10.1021/ic801917a.