氢溴酸胍

氢溴酸胍
别名	GABr
识别
CAS号	19244-98-5
性质
化学式	CH6BrN3
摩尔质量	139.98 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

氢溴酸胍是胍的氢溴酸盐，化学式为CH₆NBr。它可由碳酸胍和氢溴酸反应制得，^[1]或通过脲和溴化铵在160 °C反应得到。^[2]它和水合肼在二氧六环中回流，可以得到N,N',N''-三氨基胍氢溴酸盐。^[3]它对钙钛矿材料MAPbI₃进行后处理，可以提高其性能。^[4]

参考文献

^ Yuka E. Lewis, Tharindumala Abeywardana, Yu Hsuan Lin, Ana Galesic, Matthew R. Pratt. Synthesis of a Bis-thio-acetone (BTA) Analogue of the Lysine Isopeptide Bond and its Application to Investigate the Effects of Ubiquitination and SUMOylation on α-Synuclein Aggregation and Toxicity. ACS Chemical Biology. 2016-04-15, 11 (4): 931–942 [2021-10-23]. ISSN 1554-8929. PMC 6300141  . PMID 26726734. doi:10.1021/acschembio.5b01042. （原始内容存档于2021-10-26）（英语）.
^ Kazarnovskii, S. N.; Spasskaya, R. I. Preparation of salts of guanidine from urea and ammonium salts in the presence of silica gel. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1961. 34: 2079-2084. ISSN: 0044-4618.
^ Shouvik Mitra, Sharath Kandambeth, Bishnu P. Biswal, Abdul Khayum M., Chandan K. Choudhury, Mihir Mehta, Gagandeep Kaur, Subhrashis Banerjee, Asmita Prabhune, Sandeep Verma, Sudip Roy, Ulhas K. Kharul, Rahul Banerjee. Self-Exfoliated Guanidinium-Based Ionic Covalent Organic Nanosheets (iCONs). Journal of the American Chemical Society. 2016-03-02, 138 (8): 2823–2828 [2021-10-23]. ISSN 0002-7863. doi:10.1021/jacs.5b13533. （原始内容存档于2021-10-26）（英语）.
^ Tingting Chen, Rui He, Fan Zhang, Xia Hao, Zhipeng Xuan, Yunfan Wang, Wenwu Wang, Dewei Zhao, Jingquan Zhang, Lili Wu. GABr Post-Treatment for High-Performance MAPbI3 Solar Cells on Rigid Glass and Flexible Substrate. Nanomaterials. 2021-03-16, 11 (3): 750 [2021-10-23]. ISSN 2079-4991. doi:10.3390/nano11030750. （原始内容存档于2021-10-26）（英语）.

[1] Yuka E. Lewis, Tharindumala Abeywardana, Yu Hsuan Lin, Ana Galesic, Matthew R. Pratt. Synthesis of a Bis-thio-acetone (BTA) Analogue of the Lysine Isopeptide Bond and its Application to Investigate the Effects of Ubiquitination and SUMOylation on α-Synuclein Aggregation and Toxicity. ACS Chemical Biology. 2016-04-15, 11 (4): 931–942 [2021-10-23]. ISSN 1554-8929. PMC 6300141  . PMID 26726734. doi:10.1021/acschembio.5b01042. （原始内容存档于2021-10-26）（英语）.

[2] Kazarnovskii, S. N.; Spasskaya, R. I. Preparation of salts of guanidine from urea and ammonium salts in the presence of silica gel. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1961. 34: 2079-2084. ISSN: 0044-4618.

[3] Shouvik Mitra, Sharath Kandambeth, Bishnu P. Biswal, Abdul Khayum M., Chandan K. Choudhury, Mihir Mehta, Gagandeep Kaur, Subhrashis Banerjee, Asmita Prabhune, Sandeep Verma, Sudip Roy, Ulhas K. Kharul, Rahul Banerjee. Self-Exfoliated Guanidinium-Based Ionic Covalent Organic Nanosheets (iCONs). Journal of the American Chemical Society. 2016-03-02, 138 (8): 2823–2828 [2021-10-23]. ISSN 0002-7863. doi:10.1021/jacs.5b13533. （原始内容存档于2021-10-26）（英语）.

[4] Tingting Chen, Rui He, Fan Zhang, Xia Hao, Zhipeng Xuan, Yunfan Wang, Wenwu Wang, Dewei Zhao, Jingquan Zhang, Lili Wu. GABr Post-Treatment for High-Performance MAPbI3 Solar Cells on Rigid Glass and Flexible Substrate. Nanomaterials. 2021-03-16, 11 (3): 750 [2021-10-23]. ISSN 2079-4991. doi:10.3390/nano11030750. （原始内容存档于2021-10-26）（英语）.

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