丁酸铀酰

丁酸铀酰是一种配位化合物,化学式为UO2(C3H7COO)2,存在无水物和二水合物。[2]它可以形成配离子[UO2(C3H7COO)3][3]

丁酸铀酰
识别
CAS号 10007-92-8  checkY
性质
化学式 C8H14O6U
摩尔质量 444.22 g·mol−1
外观 黄色晶体(二水)[1]
密度 2.323 g·cm−3(二水,100 K[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

制备

丁酸铀酰可由三氧化铀丁酸在水中反应得到,从溶液中可以结晶出二水合物。[1]

参考文献

  1. ^ 1.0 1.1 1.2 A. V. Savchenkov, A. V. Vologzhanina, V. N. Serezhkin, D. V. Pushkin, L. B. Serezhkina. X-Ray diffraction and IR-spectroscopic studies of UO2(n-C3H7COO)2(H2O)2 and Mg(H2O)6[UO2(n-C3H7COO)3]2. Crystallography Reports. 2014-03, 59 (2): 190–195 [2023-02-23]. ISSN 1063-7745. doi:10.1134/S1063774514010131 (英语). 
  2. ^ Arenas, J. F.; Rojas, R. M.; Bermudez, J. Infrared spectra of butyrate complexes of uranium, bis(butyrate)​dioxouranium(VI) [UO2(C3H7COO)2], bis(butyrate)​diaquodioxouranium(VI) [UO2(C3H7COO)2(H2O)2], and tris(butyrate)​dioxouranate(VI) [UO2(C3H7COO)3]. Anales de Quimica. 1973. 69 (7-8): 869-878. ISSN 0365-4990. CODEN ANQUBU.
  3. ^ D. V. Pushkin, A. V. Vologzhanina, L. B. Serezhkina, A. V. Savchenkov, A. A. Korlyukov, V. N. Serezhkin. Synthesis, crystal structure, and IR spectral study of Na[(UO2)(C3H7COO)3] · 0.25H2O and K[(UO2)(C3H7COO)3]. Russian Journal of Inorganic Chemistry. 2012-07, 57 (7): 939–944 [2023-02-23]. ISSN 0036-0236. doi:10.1134/S0036023612070169 (英语).