3-溴-2-苯基喹啉

3-溴-2-苯基喹啉是一種有機化合物,化學式為C15H10BrN。它可以苯基溴化鎂3-溴喹啉四甲基乙二胺存在下反應得到。[1]它和苯乙炔三乙胺存在下、碘化亞銅二氯雙(三苯基膦)鈀催化下反應,可以得到2-苯基-3-苯乙炔基喹啉。[2]

3-溴-2-苯基喹啉
識別
CAS號 5332-24-1  checkY
性質
化學式 C15H10BrN
摩爾質量 284.15 g·mol−1
外觀 淺黃色固體[1]
熔點 86 °C[1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ 1.0 1.1 1.2 Fang-Fang Zhuo, Wen-Wen Xie, Yong-Xin Yang, Lei Zhang, Pei Wang, Rui Yuan, Chao-Shan Da. TMEDA-Assisted Effective Direct Ortho Arylation of Electron-Deficient N -Heteroarenes with Aromatic Grignard Reagents. The Journal of Organic Chemistry. 2013-04-05, 78 (7): 3243–3249 [2023-03-04]. ISSN 0022-3263. doi:10.1021/jo400152f. (原始內容存檔於2023-03-04) (英語). 
  2. ^ Sophie Janke, Sebastian Boldt, Karapet Ghazargan, Peter Ehlers, Alexander Villinger, Peter Langer. Synthesis of Benzoacridines and Benzophenanthridines by Regioselective Pd-Catalyzed Cross-Coupling Reactions Followed by Acid-Mediated Cycloisomerizations: Synthesis of Benzoacridines and Benzophenanthridines by Regioselective Pd-Catalyzed Cross-Coupling Reactions Followed by Acid-Mediated Cycloisomerizat. European Journal of Organic Chemistry. 2019-09-30, 2019 (36): 6177–6197 [2023-03-04]. doi:10.1002/ejoc.201900913 (英語).