3-溴-2-苯基喹啉

3-溴-2-苯基喹啉是一种有机化合物,化学式为C15H10BrN。它可以苯基溴化镁3-溴喹啉四甲基乙二胺存在下反应得到。[1]它和苯乙炔三乙胺存在下、碘化亚铜二氯双(三苯基膦)钯催化下反应,可以得到2-苯基-3-苯乙炔基喹啉。[2]

3-溴-2-苯基喹啉
识别
CAS号 5332-24-1  checkY
性质
化学式 C15H10BrN
摩尔质量 284.15 g·mol−1
外观 浅黄色固体[1]
熔点 86 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ 1.0 1.1 1.2 Fang-Fang Zhuo, Wen-Wen Xie, Yong-Xin Yang, Lei Zhang, Pei Wang, Rui Yuan, Chao-Shan Da. TMEDA-Assisted Effective Direct Ortho Arylation of Electron-Deficient N -Heteroarenes with Aromatic Grignard Reagents. The Journal of Organic Chemistry. 2013-04-05, 78 (7): 3243–3249 [2023-03-04]. ISSN 0022-3263. doi:10.1021/jo400152f. (原始内容存档于2023-03-04) (英语). 
  2. ^ Sophie Janke, Sebastian Boldt, Karapet Ghazargan, Peter Ehlers, Alexander Villinger, Peter Langer. Synthesis of Benzoacridines and Benzophenanthridines by Regioselective Pd-Catalyzed Cross-Coupling Reactions Followed by Acid-Mediated Cycloisomerizations: Synthesis of Benzoacridines and Benzophenanthridines by Regioselective Pd-Catalyzed Cross-Coupling Reactions Followed by Acid-Mediated Cycloisomerizat. European Journal of Organic Chemistry. 2019-09-30, 2019 (36): 6177–6197 [2023-03-04]. doi:10.1002/ejoc.201900913 (英语).