素馨醛
化合物
素馨醛（英语：Jasminaldehyde）是一种有机化合物，化学式为C14H18O，可用作食品香料。它可由苯甲醛和正庚醛在碱溶液（如氢氧化钠水溶液）中反应制得。[1]它在催化下可以被氢气[2]或三乙氧基硅烷[3]还原，得到2-亚苄基庚醇。
| 素馨醛 | |
|---|---|
| |
| IUPAC名 (2Z)-2-benzylideneheptanal | |
| 英文名 | Jasminaldehyde |
| 别名 | 2-亚苄基庚醛 α-戊基肉桂醛 茉莉醛 |
| 识别 | |
| CAS号 | 122-40-7  78605-96-6（2E） 101365-33-7（2Z）
|
| PubChem | 1712058 |
| ChemSpider | 1361549 |
| SMILES |
|
| ChEBI | 32318 |
| DrugBank | DB14175 |
| KEGG | C12288 |
| 性质 | |
| 化学式 | C14H18O |
| 摩尔质量 | 202.29 g·mol−1 |
| 危险性 | |
GHS危险性符号 
| |
| GHS提示词 | 警告 |
| H-术语 | H317, H411 |
| P-术语 | P261, P272, P273, P280, P302+352, P321, P333+313, P363, P391, P501 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ Manu Vashishtha, Manish Mishra, Dinesh O. Shah. A novel approach for selective cross aldol condensation using reusable NaOH-cationic micellar systems. Applied Catalysis A: General. 2013-09, 466: 38–44 [2021-07-21]. doi:10.1016/j.apcata.2013.06.015 （英语）.
- ^ Rongzhou Wang, Yuancheng Yue, Jipeng Qi, Shiyuan Liu, Ao Song, Shuping Zhuo, Ling-Bao Xing. Ambient-pressure highly active hydrogenation of ketones and aldehydes catalyzed by a metal-ligand bifunctional iridium catalyst under base-free conditions in water. Journal of Catalysis. 2021-07, 399: 1–7 [2021-07-21]. ISSN 0021-9517. doi:10.1016/j.jcat.2021.04.023.
- ^ Tingting Zheng, Junye Li, Shumiao Zhang, Benjing Xue, Hongjian Sun, Xiaoyan Li, Olaf Fuhr, Dieter Fenske. Selective C–F and C–H Activation of Fluoroarenes by Fe(PMe3)4 and Catalytic Performance of Iron Hydride in Hydrosilylation of Carbonyl Compounds. Organometallics. 2016-09-30, 35 (20): 3538–3545 [2021-07-21]. ISSN 0276-7333. doi:10.1021/acs.organomet.6b00546.