2-苯基吡啶
化合物
2-苯基吡啶是一种有机化合物，化学式为C6H5C5H4N，它是无色的粘稠液体。它可用于合成一些金属配合物，在光学领域（如有机发光二极管，OLED）上有潜在应用。[1]
| 2-苯基吡啶 | |||
|---|---|---|---|
| |||
| IUPAC名 2-Phenylpyridine | |||
| 别名 | 2-Azabiphenyl | ||
| 识别 | |||
| CAS号 | 1008-89-5 
| ||
| PubChem | 13887 | ||
| ChemSpider | 13286 | ||
| SMILES |
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| InChI |
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| InChIKey | VQGHOUODWALEFC-UHFFFAOYAS | ||
| EINECS | 213-763-1 | ||
| MeSH | C058324 | ||
| 性质 | |||
| 化学式 | C11H9N | ||
| 摩尔质量 | 155.2 g·mol−1 | ||
| 外观 | Colorless oil | ||
| 密度 | 1.086 g/mL | ||
| 沸点 | 268–270 °C | ||
| 溶解性（水） | 低 | ||
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |||
- C6H5Li + C5H5N → C6H5-C5H4N + LiH
- 4 C6H5-C5H4N + 2 IrCl3(H2O)3 → Ir2Cl2(C6H4-C5H4N)4 + 4 HCl
或进一步转化为三(2-苯基吡啶)铱。
参考文献
- ^ Eli Zysman-Colman (编). Iridium(III) in Optoelectronic and Photonics Applications. John Wiley & Sons. 2017. ISBN 978-1-119-00713-5.
- ^ Evans, J. C. W.; Allen, C. F. H. 2-Phenylpyridine. Organic Syntheses. 1938, 18: 70. doi:10.15227/orgsyn.018.0070.
- ^ Lamansky, S.; Djurovich, P.; Murphy, D.; et al. Synthesis and Characterization of Phosphorescent Cyclometalated Iridium Complexes. Inorganic Chemistry. 2001, 40 (7): 1704–1711. PMID 11261983. doi:10.1021/ic0008969.
- ^ Kip A. Teegardin, Jimmie D. Weaver. Preparation of Fac-Tris(2-Phenylpyridinato) Iridium(III). Org. Synth. 2018, 95: 29. doi:10.15227/orgsyn.095.0029
.
延伸阅读
- Zhou, Guijiang; Wong, Wai-Yeung; Yang, Xiaolong. New Design Tactics in OLEDs Using Functionalized 2-Phenylpyridine-Type Cyclometalates of Iridium(III) and Platinum(II). Chemistry: An Asian Journal. 2011, 6 (7): 1706–1727. doi:10.1002/asia.201000928.